Kinetic aspects of stereoselectivity in hydrogenation of fatty acids

被引：7

作者：

Murzin, Dmitry Yu. ^{[1
]}

Simakova, Irina L. ^{[2
]}

机构：

[1] Abo Akad Univ, Lab Ind Chem & React Engn, SF-20500 Turku, Finland

[2] Boreskov Inst Catalysis, Novosibirsk, Russia

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 286卷 / 1-2期

基金：

芬兰科学院;

关键词：

hydrogenation; fatty acids; stereoselectivity; kinetics;

D O I：

10.1016/j.molcata.2008.02.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetic peculiarities of stereoselectivity in hydrogenation of fatty acids are discussed. The reaction mechanism should be able to account for independence of the reaction rate on hydrogen pressure and conversion, stereoselectivity on conversion as well as an increase in cis/trans ratio with pressure increase. Various mechanisms advanced in the literature for formation of cis- and trans mono-unsaturated acids and their derivatives are considered, showing behavior contradicting with experiments. A reaction mechanism is proposed, which is consistent with experimental observations. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：156 / 161

页数：6

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