Methane oxyforming for synthesis gas production

被引:200
作者
York, Andrew P. E.
Xiao, Tian-Cun
Green, Malcolm L. H.
Claridge, John B.
机构
[1] Univ Oxford, Inorgan Chem Lab, Wolfson Catalysis Ctr, Oxford OX1 3QR, England
[2] Univ Liverpool, Dept Chem, Liverpool L69 72D, Merseyside, England
来源
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2007年 / 49卷 / 04期
关键词
methane; dry reforming; steam reforming; partial oxidation; synthesis gas;
D O I
10.1080/01614940701583315
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This article is concerned with the reforming of methane to synthesis gas; a review of the steam reforming Rxn is presented, and the dry reforming and partial oxidation Rxns introduced. Collectively, these processes are known as " oxyforming." A background to oxyforming, industrial practice, and some of the most important latest developments will be presented, along with a section on the uses of synthesis gas. The current understanding of the Rxn mechanisms for the three processes and the problem of deactivation by carbon deposition will be discussed in detail. Finally, the economics of synfuel production will be addressed and compared with the production of other fuels, and the future directions and outlook for oxyforming will be forwarded. This article should allow the reader to make comparisons between these three important industrial reactions.
引用
收藏
页码:511 / 560
页数:50
相关论文
共 289 条
[1]   Mechanisms for catalytic carbon nanofiber growth studied by ab initio density functional theory calculations [J].
Abild-Pedersen, F ;
Norskov, JK ;
Rostrup-Nielsen, JR ;
Sehested, J ;
Helveg, S .
PHYSICAL REVIEW B, 2006, 73 (11)
[2]   CATALYTIC DEACTIVATION ON METHANE STEAM REFORMING CATALYSTS .2. KINETIC-STUDY [J].
AGNELLI, ME ;
PONZI, EN ;
YERAMIAN, AA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1987, 26 (08) :1707-1713
[3]  
AGRANAT BD, 1976, KINET KATAL, V17, P1241
[4]   OXIDATIVE DIMERIZATION OF METHANE OVER BACO3, SRCO3 AND THESE CATALYSTS PROMOTED WITH ALKALI [J].
AIKA, K ;
MORIYAMA, T ;
TAKASAKI, N ;
IWAMATSU, E .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (15) :1210-1211
[5]   KINETICS OF THE METHANE-STEAM REACTION [J].
AKERS, WW ;
CAMP, DP .
AICHE JOURNAL, 1955, 1 (04) :471-475
[6]   KINETICS OF METHANE-STEAM REACTION [J].
ALLEN, DW ;
GERHARD, ER ;
LIKINS, MR .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1975, 14 (03) :256-259
[7]   SYNTHESIS GAS-PRODUCTION FROM METHANE OVER AN IRON ELECTRODE IN A SOLID-ELECTROLYTE CELL [J].
ALQAHTANY, H ;
ENG, D ;
STOUKIDES, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (06) :1677-1681
[8]   SIMULATION OF METHANE PARTIAL OXIDATION OVER SILICA-SUPPORTED MOO3 AND V2O5 [J].
AMIRIDIS, MD ;
REKOSKE, JE ;
DUMESIC, JA ;
RUDD, DF ;
SPENCER, ND ;
PEREIRA, CJ .
AICHE JOURNAL, 1991, 37 (01) :87-97
[9]  
ANGELLI ME, 1987, IND ENG CHEM RES, V26, P1704
[10]  
[Anonymous], EPIC QUEST OIL MONEY