Efficient One-to-One Coupling of Easily Available 1,3-Dienes with Carbon Dioxide

被引：115

作者：

Takaya, Jun ^{[1
]}

Sasano, Kota ^{[1
]}

Iwasawa, Nobuharu ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 07期

关键词：

PALLADIUM COMPLEXES; CATALYZED CARBOXYLATION; TRANSFER HYDROGENATION; QUATERNARY CENTERS; ALLYL STANNANES; METAL-COMPLEXES; CO2; BUTADIENE; 1,3-BUTADIENE; NICKEL;

D O I：

10.1021/ol2002094

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient one-to-one coupling reaction of atmospheric pressure carbon dioxide with 1,3-dienes is realized for the first time through PSiP-pincer type palladium-catalyzed hydrocarboxylation. The reaction is applicable to various 1,3-dienes including easily available chemical feedstock such as 1,3-butadiene and Isoprene. This protocol affords a highly useful method for the synthesis of beta,gamma-unsaturated carboxylic acid derivatives from CO(2).

引用

页码：1698 / 1701

页数：4

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