Transformation of a spherical supramolecular dendrimer into a pyramidal columnar supramolecular dendrimer mediated by the fluorophobic effect

被引：126

作者：

Percec, V ^{[1
]}

Glodde, M

Johansson, G

Balagurusamy, VSK

Heiney, PA

机构：

[1] Univ Penn, Roy & Diana Vagelos Labs, Dept Chem, Res Struct Matter Lab, Philadelphia, PA 19104 USA

[2] Univ Penn, Dept Phys & Astron, Res Struct Matter Lab, Philadelphia, PA 19104 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 36期

关键词：

dendrimers; fluorophobic effect; liquid crystals; self-assembly;

D O I：

10.1002/anie.200351804

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Shape control: Fluorination of the n-dodecan-l-yloxy groups of the amphiphilic (3,4,5)2G2-CO2Me monodendron changes the shape of the monodendron from an all-trans-conical to an all-gauche-crown or all-trans-tapered conformation as well as the mode of self-assembly from a spherical to a pyramidal columnar supra-molecular dendrimer (see schematic representation).

引用

页码：4338 / 4342

页数：5

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