Cationic effect in agueous solutions of 1:1 electrolytes by Raman spectral data

被引：19

作者：

Chumaevskii, NA ^{[1
]}

Rodnikova, MN ^{[1
]}

Sirotkin, DA ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2001年 / 91卷 / 1-3期

关键词：

D O I：

10.1016/S0167-7322(01)00148-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New experimental data by Raman spectral analysis of light and heavy water and also the aqueous solutions of 1:1 electrolytes were received. It is very important that the water band of O-H (O-D) stretching vibrations have five but not three components at normal conditions of study. Our explanations of experimental facts are based on the presence of the spatial hydrogen network in liquid water and electrolyte solutions. The mechanism of defect formation as model of rotational reorientations of the water molecules was suggested. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：81 / 90

页数：10