Cross-coupling reactions of allylic alcohols in water

被引：49

作者：

Manabe, K ^{[1
]}

Nakada, K ^{[1
]}

Aoyama, N ^{[1
]}

Kobayashi, S ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, HFRE Div, ERATO,JST,Bunkyo Ku, Tokyo 1130033, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2005年 / 347卷 / 11-13期

关键词：

allylic alcohols; allylic arenes; boronic acids; cross-coupling; palladium; water;

D O I：

10.1002/adsc.200505135

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Palladium- catalyzed cross-coupling reactions of allylic alcohols and arylboronic acids in water are described. The reactions proceeded smoothly in water at reflux using catalytic amounts of [Pd(allyl)Cl](2) and PPh3. Addition of a catalytic amount of a base allowed the reaction to proceed even at lower temperatures.

引用

页码：1499 / 1503

页数：5

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