Efficient Mn-Cu and Mn-Co-TEMPO-catalysed oxidation of alcohols into aldehydes and ketones by oxygen under mild conditions

被引：154

作者：

Cecchetto, A

Fontana, F

Minisci, F

Recupero, F

机构：

[1] Politecn Milan, Dipartimento Chim, I-20131 Milan, Italy

[2] Univ Bergamo, Dipartimento Ingn, I-24044 Dalmine BG, Italy

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(01)01245-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A catalytic amount of Mn(II)-Co(II) or Mn(II)-Cu(II) nitrates in combination with TEMPO allows the selective oxidation of primary and secondary alcohols to aldehydes and ketones by oxygen under very mild conditions. Mechanistic aspects are discussed. The catalyst can be considered the cheapest and the most effective for the selective aerobic oxidation of alcohols. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：6651 / 6653

页数：3

共 10 条

[1]

Anelli P. L., 1990, ORG SYNTH, V69, P212

[2] OXIDATION OF DIOLS WITH ALKALI HYPOCHLORITES CATALYZED BY OXAMMONIUM SALTS UNDER 2-PHASE CONDITIONS [J].