Total-internal-reflection broad-bandwidth sum frequency generation spectroscopy of hexadecanethiol adsorbed on thin gold film deposited on CaF2

被引：9

作者：

Nishi, N ^{[1
]}

Hobara, D ^{[1
]}

Yamamoto, M ^{[1
]}

Kakiuchi, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Kyoto 6068501, Japan

来源：

ANALYTICAL SCIENCES | 2003年 / 19卷 / 06期

关键词：

D O I：

10.2116/analsci.19.887

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Sum frequency vibrational spectra for hexadecanethiol (HDT) adsorbed on thin gold film deposited on the surface of a CaF2 prism have been measured using total-internal reflection broad-bandwidth sum frequency generation (TIR-BBSFG) spectroscopy. The bands attributed to the CH3 Symmetric and asymmetric stretching vibrational modes were observed in the sum frequency vibrational spectra. The orientation of the methyl groups was analyzed using the ratio of the intensities of the two modes. The methyl groups of HDT on the thin gold film were much more randomly orientated than those on Au(111).

引用

页码：887 / 890

页数：4

共 44 条

[1] TOTAL INTERNAL-REFLECTION FLUORESCENCE [J].

AXELROD, D ;

BURGHARDT, TP ;

THOMPSON, NL .

ANNUAL REVIEW OF BIOPHYSICS AND BIOENGINEERING, 1984, 13 :247-268

[2] QUANTITATIVE-ANALYSIS OF MONOLAYER COMPOSITION BY SUM-FREQUENCY VIBRATIONAL SPECTROSCOPY [J].

BAIN, CD ;

DAVIES, PB ;

ONG, TH ;

WARD, RN ;

BROWN, MA .

LANGMUIR, 1991, 7 (08) :1563-1566

[3] Sum-frequency vibrational spectroscopy of soluble surfactants at the air/water interface [J].

Bell, GR ;

Bain, CD ;

Ward, RN .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (04) :515-523

[4] Thermal treatment of n-alkanethiolate monolayers on gold, as observed by infrared spectroscopy [J].

Bensebaa, F ;

Ellis, TH ;

Badia, A ;

Lennox, RB .

LANGMUIR, 1998, 14 (09) :2361-2367

[5] INTERFERENCE BETWEEN 2ND-HARMONIC GENERATION FROM A SUBSTRATE AND FROM AN ADSORBATE LAYER [J].

BERKOVIC, G ;

SHEN, YR ;

MAROWSKY, G ;

STEINHOFF, R .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1989, 6 (02) :205-208

[6] TOTAL REFLECTION PHENOMENA IN SECOND-HARMONIC GENERATION OF LIGHT [J].

BLOEMBER.N ;

SIMON, HJ ;

LEE, CH .

PHYSICAL REVIEW, 1969, 181 (03) :1261-&

[7] Sum-frequency generation from thiophenol on silver in the mid and far-IR [J].

Braun, R ;

Casson, BD ;

Bain, CD ;

van der Ham, EWM ;

Vrehen, QHF ;

Eliel, ER ;

Briggs, AM ;

Davies, PB .

JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (09) :4634-4640

[8] STUDIES OF ALKANE WATER INTERFACES BY TOTAL INTERNAL-REFLECTION 2ND-HARMONIC GENERATION [J].

CONBOY, JC ;

DASCHBACH, JL ;

RICHMOND, GL .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (39) :9688-9692

[9]

Epple M, 2002, LANGMUIR, V18, P773, DOI 10.1021/la0l09819

[10] OPTICAL 2ND-HARMONIC GENERATION FROM ADSORBATE LAYERS IN TOTAL-REFLECTION GEOMETRY [J].

FELDERHOF, BU ;

BRATZ, A ;

MAROWSKY, G ;

RODERS, O ;

SIEVERDES, F .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1993, 10 (10) :1824-1833

← 1 2 3 4 5 →