Transition assignments in the ultraviolet-visible absorption and magnetic circular dichroism spectra of phthalocyanines

被引：56

作者：

Mack, J ^{[1
]}

Stillman, MJ ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 04期

关键词：

D O I：

10.1021/ic0009829

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In a recent paper it has been proposed that the four-orbital model of Gouterman should be replaced by a new band assignment scheme for the MPc UV-visible absorption spectrum. Since this proposed assignment scheme would alter the basis for the spectral analysis of a wide range of complexes, its validity is tested against experimental evidence from other spectroscopic techniques such as magnetic circular dichroism spectroscopy.

引用

页码：812 / 814

页数：3

共 43 条

[1]

[Anonymous], PHTHALOCYANINES PROP

[2]

[Anonymous], 1989, Phthalocyanines: Properties and Applications

[3] CALCULATED STRUCTURES AND ELECTRONIC ABSORPTION-SPECTROSCOPY FOR MAGNESIUM PHTHALOCYANINE AND ITS ANION-RADICAL [J].

CORY, MG ;

HIROSE, H ;

ZERNER, MC .

INORGANIC CHEMISTRY, 1995, 34 (11) :2969-2979

[4] PORPHYRINS .15. VAPOR ABSORPTION SPECTRA AND STABILITY . PHTHALOCYANINES [J].

EDWARDS, L ;

GOUTERMAN, M .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1970, 33 (02) :292-+

[5] MICROCOMPUTER-AIDED CHEMISTRY .5. INTERACTIVE COMPUTING FOR INSTRUMENT CONTROL AND DATA-ANALYSIS IN PHOTOCHEMICAL STUDIES [J].

GASYNA, Z ;

BROWETT, WR ;

NYOKONG, T ;

KITCHENHAM, R ;

STILLMAN, MJ .

CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 1989, 5 (03) :233-246

[6] SPECTRA OF PORPHYRINS .2. 4 ORBITAL MODEL [J].

GOUTERMAN, M ;

SNYDER, LC ;

WAGNIERE, GH .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1963, 11 (02) :108-&

[7]

Gouterman M, 1972, J MOL SPECTROSC, V44, P37

[8]

Gouterman M., 1978, PORPHYRINS, P1, DOI DOI 10.1016/B978-0-12-220103-5.50008-8

[9] SEMIEMPIRICAL MOLECULAR-ORBITAL STUDIES OF PHTHALOCYANINES .1. ELECTRONIC-STRUCTURE AND EXCITED-STATES OF PHTHALOCYANINE, H2PC [J].

HENRIKSSON, A ;

SUNDBOM, M .

THEORETICA CHIMICA ACTA, 1972, 27 (03) :213-+

[10] PERTURBATIONS BETWEEN ELECTRONIC STATES IN AROMATIC AND HETEROAROMATIC MOLECULES [J].

HOCHSTRA.RM ;

MARZZACC.C .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (03) :971-&

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