Construction and optimization of a low cost reactor for the photodegradation of organic matter from natural waters and its application for the study of copper speciation by voltammetry.

被引:17
作者
Campos, MLAM [1 ]
Mello, LC [1 ]
Zanette, DR [1 ]
Sierra, MMD [1 ]
Bendo, A [1 ]
机构
[1] Univ Fed Santa Catarina, Dept Quim, BR-88040900 Florianopolis, SC, Brazil
来源
QUIMICA NOVA | 2001年 / 24卷 / 02期
关键词
photodegradation; organic matter; trace metal speciation;
D O I
10.1590/S0100-40422001000200018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This work describes the construction of a home-made low-cost reactor, using easily available materials, capable of destroying efficiently dissolved organic matter. Just 30 minutes of irradiation were sufficient to destroy more than 99% of the humic acids present in a solution of 4 mg C L-1. Copper speciation was evaluated in natural waters of different salinities to test the reactor's efficiency in destroying organically complexed metal species. The effect of the organic matter concentration, salinity, dissolved oxygen and temperature in the photo-oxidation process is discussed.
引用
收藏
页码:257 / 261
页数:5
相关论文
共 19 条
[1]   Stripping voltammetry for the determination of trace metal speciation and in-situ measurements of trace metal distributions in marine waters [J].
Achterberg, EP ;
Braungardt, C .
ANALYTICA CHIMICA ACTA, 1999, 400 :381-397
[2]   IN-LINE ULTRAVIOLET-DIGESTION OF NATURAL-WATER SAMPLES FOR TRACE-METAL DETERMINATION USING AN AUTOMATED VOLTAMMETRIC SYSTEM [J].
ACHTERBERG, EP ;
VAN DEN BERG, CMG .
ANALYTICA CHIMICA ACTA, 1994, 291 (03) :213-232
[3]   PHOTOCATALYTIC DEGRADATION OF PHENOL AND CHLORINATED PHENOLS USING AG-TIO2 IN A SLURRY REACTOR [J].
ALBERICI, RM ;
JARDIM, WF .
WATER RESEARCH, 1994, 28 (08) :1845-1849
[4]  
CAMPOS MLAM, 1994, ANAL CHIM ACTA, V284, P481
[5]  
Chester R., 1990, MARINE GEOCHEMISTRY
[6]   PHOTOCHEMICAL ASPECTS RELATED TO HUMIC SUBSTANCES [J].
FRIMMEL, FH .
ENVIRONMENT INTERNATIONAL, 1994, 20 (03) :373-385
[7]  
Grasshoff K., 1976, Methods of Seawater Analysis, V2nd
[8]   SHORT-TERM TOXICITY TEST USING ESCHERICHIA-COLI - MONITORING CO2 PRODUCTION BY FLOW-INJECTION ANALYSIS [J].
JARDIM, WF ;
PASQUINI, C ;
GUIMARAES, JR ;
DEFARIA, LC .
WATER RESEARCH, 1990, 24 (03) :351-354
[9]   PHOTODEGRADATION OF SOME NATURALLY-OCCURRING ORGANIC-COMPOUNDS AND THEIR METAL-COMPLEXES [J].
JARDIM, WF ;
CAMPOS, MLAM .
SCIENCE OF THE TOTAL ENVIRONMENT, 1988, 75 (2-3) :243-248
[10]   OXYGEN-CONSUMPTION FROM NATURAL-WATERS BY PHOTO-OXIDIZING PROCESSES [J].
LAANE, RWPM ;
GIESKES, WWC ;
KRAAY, GW ;
EVERSDIJK, A .
NETHERLANDS JOURNAL OF SEA RESEARCH, 1985, 19 (02) :125-128