Novel gelatinous shape-stabilized phase change materials with high heat storage density

被引:59
作者
Zhang, Xiaoxing [1 ]
Deng, Pengfei [2 ,3 ]
Feng, Rongxiu [1 ]
Song, Jian [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
[2] Hainan Normal Univ, Sch Chem & Chem Engn, Haikou 571158, Peoples R China
[3] Hainan Prov Key Lab Trop Pharmaceut Herb Che, Haikou 571158, Peoples R China
关键词
Phase change materials; Paraffin; Polyol acetal derivatives; Gelator; Heat storage density; THERMAL-ENERGY STORAGE; PARAFFIN WAXES; POLYETHYLENE; TEMPERATURE; PERFORMANCE; SYSTEMS;
D O I
10.1016/j.solmat.2011.01.025
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
080707 [能源环境工程]; 082001 [油气井工程];
摘要
A series of polyol acetal derivatives were synthesized through condensation reactions of aromatic aldehyde with polyols, including sorbitol, mannitol, xylitol, and pentaerythritol. They were examined as gelators in the formation of paraffin-based shape-stabilized phase change materials (PCMs), in which 1,3:2,4-di-(4-methyl) benzylidene sorbitol (MOBS) exhibited excellent thermal stability. Three-dimensional netted structural phase change materials were obtained by paraffin doped with different gelators, which were thermally stable so that no leakage of paraffin occurs even under higher temperature than the melting point of paraffin. It was found that PCMs doped with 3 wt% expanded and exfoliated graphite (EG) exhibited better thermal conductivity, similar phase change temperature and heat storage density. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1213 / 1218
页数:6
相关论文
共 19 条
[1]
LOW-TEMPERATURE LATENT-HEAT THERMAL-ENERGY STORAGE - HEAT-STORAGE MATERIALS [J].
ABHAT, A .
SOLAR ENERGY, 1983, 30 (04) :313-332
[2]
Applicability of frozen gels from ultra high molecular weight polyethylene and paraffin waxes as shape persistent solid/liquid phase change materials [J].
Beginn, U .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2003, 288 (03) :245-251
[3]
Thermal energy storage systems as a key technology in energy conservation [J].
Dincer, I .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2002, 26 (07) :567-588
[4]
FENG RX, 2007, T TIANJIN U, P35
[5]
Microencapsulated PCM thermal-energy storage system [J].
Hawlader, MNA ;
Uddin, MS ;
Khin, MM .
APPLIED ENERGY, 2003, 74 (1-2) :195-202
[6]
CHARACTERIZATION OF ALKANES AND PARAFFIN WAXES FOR APPLICATION AS PHASE-CHANGE ENERGY-STORAGE MEDIUM [J].
HIMRAN, S ;
SUWONO, A ;
MANSOORI, GA .
ENERGY SOURCES, 1994, 16 (01) :117-128
[7]
Preparation of polyethylene-paraffin compound as a form-stable solid-liquid phase change material [J].
Hong, Y ;
Ge, XS .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 64 (01) :37-44
[8]
The viability of thermal energy storage [J].
Kaygusuz, K .
ENERGY SOURCES, 1999, 21 (08) :745-755
[9]
Crystalline morphology in high-density polyethylene/paraffin blend for thermal energy storage [J].
Lee, CH ;
Choi, HK .
POLYMER COMPOSITES, 1998, 19 (06) :704-708
[10]
Preparation and thermal properties of form stable paraffin phase change material encapsulation [J].
Liu Xing ;
Liu Hongyan ;
Wang ShuJun ;
Zhang Lu ;
Cheng Hua .
ENERGY CONVERSION AND MANAGEMENT, 2006, 47 (15-16) :2515-2522