Surface-enhanced Raman scattering (SERS) spectra of sodium benzoate and 4-picoline in Ag colloids prepared by γ-irradiation

被引:23
作者
Choi, SH
Park, HG
机构
[1] Hannam Univ, Dept Chem, Taejon 306791, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon, South Korea
关键词
surface-enhanced Raman scattering (SERS) spectra; Ag colloids; gamma-Irradiation; chemical reduction; sodium benzoate; 4-picoline;
D O I
10.1016/j.apsusc.2004.09.051
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
PVP-protected silver colloids were prepared by gamma-irradiation and chemical reduction method. Surface-enhanced Raman scattering (SERS) spectra of sodium benzoate and 4-picoline in Ag colloids prepared by gamma-irradiation were recorded. The SERS spectra of sodium benzoate were successfully recorded in Ag colloids, whereas the Raman spectra did not appear without Ag colloids. The Raman spectra of 4-picoline were not detected without Ag colloids, while the SERS spectra of 4-picoline were increased by adding Ag colloids. The carboxylate group of sodium benzoate and N donor of 4-picoline were adsorbed on the surface of Ag nanoparticles. (c) 2004 Elsevier B.V. All fights reserved.
引用
收藏
页码:76 / 81
页数:6
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