A new route toward ZnO hollow spheres by a base-erosion mechanism

被引：73

作者：

Chen, Zhitao ^{[1
]}

Gao, Lian ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 02期

关键词：

D O I：

10.1021/cg070277b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this paper, thermal treatment of Zn(NH3)(4)(2+) precursor in ethanol solvent leading to the formation of the ZnO hollow spheres is reported. It was demonstrated that the pH value of the initial mixture and the volume ratio of the ethanol with the solution plays the key function in the formation of hollow spheres. Transmission electron microscopy and scanning electron microscopy images showed that hollow spheres of similar to 600 nm in diameter were built by ZnO nanorods. On the basis of experimental results, a possible formation mechanism in the growth processes is discussed.

引用

页码：460 / 464

页数：5

共 40 条

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