Palladium-catalyzed 1,2-oxidation of allenes

被引：28

作者：

Backvall, JE

Jonasson, C

机构：

[1] Department of Organic Chemistry, University of Uppsala, Box 531

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(96)02295-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed oxidation of allenes with palladium acetate as the catalyst and p-benzoquinone as the oxidant in the presence of lithium bromide afforded 1,2-dibromides in a regioselective reaction. The reaction proceeds via a (pi-allyl)palladium intermediate. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：291 / 294

页数：4

共 33 条

[1] CARBOPALLADATION OF ALLENIC HYDROCARBONS - A NEW WAY TO FUNCTIONALIZED STYRENES AND 1,3-BUTADIENES [J].