Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47

被引：933

作者：

Bourrelly, S

Llewellyn, PL ^{[1
]}

Serre, C

Millange, F

Loiseau, T

Férey, G

机构：

[1] Univ Aix Marseille 1, MADIREL, CNRS UMR 6121, Ctr St Jerome, F-13397 Marseille, France

[2] Univ Versailles St Quentin En Yvelines, Inst Lavoisier, UMR CNRS 8637, F-78035 Versailles, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 39期

关键词：

D O I：

10.1021/ja054668v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A distinct step in the isotherm occurs during the adsorption of CO 2 on MIL-53 at 304 K. Such behavior is neither observed during the adsorption of CH 4 on MIL-53 nor during the adsorption on the isostructural MIL-47. This phenomenon seems to be due to a different mechanism than that of previous adsorption steps on MOF samples. It is suggested that a breathing behavior is induced in MIL-53 during CO 2 adsorption. Copyright © 2005 American Chemical Society.

引用

页码：13519 / 13521

页数：3

共 30 条

[1] Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO
[2] 2-Y
[3] GRAVIMETRIC MEASUREMENT OF BINARY GAS-ADSORPTION EQUILIBRIA OF METHANE-CARBON DIOXIDE MIXTURES ON ACTIVATED CARBON
BUSS, E
[J]. GAS SEPARATION & PURIFICATION, 1995, 9 (03): : 189 - 197
[4] Calorimetric heats of adsorption and adsorption isotherms .1. O-2, N-2, Ar, CO2, CH4, C2H6 and SF6 on silicalite
Dunne, JA
Mariwals, R
Rao, M
Sircar, S
Gorte, RJ
Myers, AL
[J]. LANGMUIR, 1996, 12 (24) : 5888 - 5895
[5] Calorimetric heats of adsorption and adsorption isotherms .2. O-2, N-2, Ar, CO2, CH4, C2H6, and SF6 on NaX, H-ZSM-5, and Na-ZSM-5 zeolites
Dunne, JA
Rao, M
Sircar, S
Gorte, RJ
Myers, AL
[J]. LANGMUIR, 1996, 12 (24) : 5896 - 5904
[6] Design of new materials for methane storage
Düren, T
Sarkisov, L
Yaghi, OM
Snurr, RQ
[J]. LANGMUIR, 2004, 20 (07) : 2683 - 2689
[7] Microporous manganese formate: A simple metal-organic porous material with high framework stability and highly selective gas sorption properties
Dybtsev, DN
Chun, H
Yoon, SH
Kim, D
Kim, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) : 32 - 33
[8] Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+), MIL-53
Férey, G
Latroche, M
Serre, C
Millange, F
Loiseau, T
Percheron-Guégan, A
[J]. CHEMICAL COMMUNICATIONS, 2003, (24) : 2976 - 2977
[9] Crystallized frameworks with giant pores:: Are there limits to the possible?
Férey, G
Mellot-Draznieks, C
Serre, C
Millange, F
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) : 217 - 225
[10] Adsorption of gases and vapors on nanoporous Ni2(4,4′-bipyridine)3(NO3)4 metal-organic framework materials templated with methanol and ethanol:: Structural effects in adsorption kinetics
Fletcher, AJ
Cussen, EJ
Bradshaw, D
Rosseinsky, MJ
Thomas, KM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (31) : 9750 - 9759

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