Synthesis and structure of [18-MCCuII(N)pko-6]6+:: A new member of anion encapsulating metallamacrocyles

被引：26

作者：

Afrati, T

Dendrinou-Samara, C

Zaleski, CM

Kampf, JW

Pecoraro, VL

Kessissoglou, DP

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[2] Aristotle Univ Thessaloniki, Dept Gen & Inorgan Chem, Thessaloniki 54124, Greece

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 12期

基金：

美国国家科学基金会;

关键词：

metallamacrocycle; copper complex; crystal structure;

D O I：

10.1016/j.inoche.2005.09.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of copper(II) perchlorate with di-2-pyridyl ketone oxime yields the first 18-MC-6 complex with M-N-O connectivity, [Cu-6(pko)(6)ClO4(CH3CN)(6)] [Cu-6(pko)(6)(ClO4)(3)(CH3CN)(4)]- 8ClO(4) (.) 14CH(3)CN - H2O 1. In the solid state the cationic complex encapsulates a perchlorate anion within the central cavity. Magnetic susceptibility measurements reveal that the complex is diamagnetic. EPR measurements indicate that the complex dissociates in DMF. (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：1173 / 1176

页数：4

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