Ion pairing in transition-metal organometallic chemistry

被引：450

作者：

Macchioni, A ^{[1
]}

机构：

[1] Univ Perugia, Dept Chem, I-06123 Perugia, Italy

来源：

CHEMICAL REVIEWS | 2005年 / 105卷 / 06期

关键词：

D O I：

10.1021/cr0300439

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview of ion pairing in transition metal organometallic chemistry is given. Main group metal and transition metal complex ion pairs are distinguished on the basis of the nature of the metal-ligand bond. Focus is on the effect of ion pairing on the structure and reactivity of transition metal organometallic ion pairs in cases where the counterion still maintains most of its original charge, and consequently does not significantly share electron density with the metal center. The types of reactions covered in which ion pairing plays a critical role include formation and heterolytic splitting of dihydrogen metal complexes, olefin polymerization, and Diels-Alder, hydrogenation, and carbonylation processes.

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页码：2039 / 2073

页数：35

相关论文

共 464 条

[1] (Salen)Mn(III)-catalyzed epoxidation reaction as a multichannel process with different spin states. Electronic tuning of asymmetric catalysis: A theoretical study [J].

Abashkin, YG ;

Collins, JR ;

Burt, SK .

INORGANIC CHEMISTRY, 2001, 40 (16) :4040-4048

[2] CONDUCTIVITY OF TETRA-ALKYLAMMONIUM SALTS IN POLYAROMATIC SOLVENTS [J].

ABBOTT, AP ;

SCHIFFRIN, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (09) :1453-1459

[3] Intra- and inter-ion-pair protonic-hydridic bonding in polyhydridobis(phosphine)rhenates [J].

Abdur-Rashid, K ;

Lough, AJ ;

Morris, RH .

CANADIAN JOURNAL OF CHEMISTRY, 2001, 79 (5-6) :964-976

[4] Intermolecular proton-hydride bonding in ion pairs:: Synthesis and structural properties of [K(Q)][MH5(PiPr3)2] (M = Os, Ru; Q=18-crown-6, 1-aza-18-crown-6, 1,10-diaza-18-crown-6) [J].

Abdur-Rashid, K ;

Gusev, DG ;

Lough, AJ ;

Morris, RH .

ORGANOMETALLICS, 2000, 19 (05) :834-843

[5] Organizing chain structures by use of proton-hydride bonding.: The single-crystal X-ray diffraction structures of [K(Q)][Os(H)5(PiPr3)2] and [K(Q)][Ir(H)4(PiPr3)2], Q = 18-crown-6 and 1,10-diaza-18-crown-6 [J].

Abdur-Rashid, K ;

Gusev, DG ;

Landau, SE ;

Lough, AJ ;

Morris, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (45) :11826-11827

[6] An acidity scale for phosphorus-containing compounds including metal hydrides and dihydrogen complexes in THF: Toward the unification of acidity scales [J].

Abdur-Rashid, K ;

Fong, TP ;

Greaves, B ;

Gusev, DG ;

Hinman, JG ;

Landau, SE ;

Lough, AJ ;

Morris, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (38) :9155-9171

[7] Polynuclear catalysis: Enhancement of enchainment cooperativity between different single-site olefin polymerization catalysts by ion pairing with a binuclear cocatalyst [J].

Abramo, GP ;

Li, LT ;

Marks, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :13966-13967

[8] cis-stilbene and (1α,2β,3α)-(2-ethenyl-3-methoxycyclopropyl)benzene as mechanistic probes in the MnIII(salen)-catalyzed epoxidation:: Influence of the oxygen source and the counterion on the diastereoselectivity of the competitive concerted and radical-type oxygen transfer [J].

Adam, W ;

Roschmann, KJ ;

Saha-Möller, CR ;

Seebach, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (18) :5068-5073

[9]

Adam W, 2000, EUR J ORG CHEM, V2000, P3519

[10] THE ION-PAIR MECHANISM IN SQUARE-PLANAR SUBSTITUTION - DISPLACEMENT OF DIMETHYL-SULFOXIDE FROM CHLORO(DIMETHYL SULFOXIDE) (N,N,N',N'-TETRAMETHYLDIAMINOETHANE)PLATINUM(II) SALTS BY HALIDE-IONS IN DICHLOROMETHANE SOLUTION [J].

ALIBRANDI, G ;

ROMEO, R ;

SCOLARO, LM ;

TOBE, ML .

INORGANIC CHEMISTRY, 1992, 31 (24) :5061-5066

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