Structure-Related Electrochemistry of Sulfur-Poly(acrylonitrile) Composite Cathode Materials for Rechargeable Lithium Batteries

被引：337

作者：

Fanous, Jean ^{[1
]}

Wegner, Marcus ^{[1
]}

Grimminger, Jens ^{[1
]}

Andresen, Anne ^{[1
]}

Buchmeiser, Michael R. ^{[2
]}

机构：

[1] Robert Bosch GmbH, Corp Sector Res & Adv Engn CR ARC1, D-70049 Stuttgart, Germany

[2] Univ Stuttgart, Inst Polymer Chem, D-70569 Stuttgart, Germany

来源：

CHEMISTRY OF MATERIALS | 2011年 / 23卷 / 22期

关键词：

cathode materials; polymer-sulfur composite; rechargeable lithium battery; conducting polymer; poly(acrylonitrile); POLYMERS; STORAGE;

D O I：

10.1021/cm202467u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure of sulfur-poly(acrylonitrile)based Li-sulfur batteries is elucidated and correlated with the electrochemical performance of such devices. Apart from the poly(acrylonitrile)-derived backbone, thioamide as well as poly(sulfide) structures are proposed. Furthermore, the intermediary formation of S-8 during cycling and the role of the electrolyte in its reintegration during charging into are addressed. In summary, a comprehensive picture of the chemistry and electrochemistry of Li-sulfur batteries is presented.

引用

页码：5024 / 5028

页数：5

共 35 条

[1]

[Anonymous], 2010, ANGEW CHEM-GER EDIT, DOI [DOI 10.1002/ANIE.200907324, DOI 10.1002/ANGE.200907324]

[2] XPS AND LAXS STUDY OF 1,3-THIAZOLIDINE-2-THIONE AND ITS COMPLEXES WITH CO(II) AND ZN(II) [J].

ATZEI, D ;

DEFILIPPO, D ;

ROSSI, A ;

CAMINITI, R ;

SADUN, C .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1995, 51 (01) :11-20

[3] CHEMI-LUMINESCENCE STUDIES OF THE LOW-TEMPERATURE THERMOOXIDATION OF POLY(PHENYLENE SULFIDE) [J].

BRAUMAN, SK .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (10) :3285-3302

[4] PI-STAR[-PI SHAKEUP SATELLITES FOR THE ANALYSIS OF STRUCTURE AND BONDING IN AROMATIC POLYMERS BY X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

GARDELLA, JA ;

FERGUSON, SA ;

CHIN, RL .

APPLIED SPECTROSCOPY, 1986, 40 (02) :224-232

[5] HEAVY-METAL CHELATES OF ALPHA-CYANO-BETA-AMINO-DITHIOACRYLATES [J].

HARTUNG, J ;

WEBER, G ;

BEYER, L ;

SZARGAN, R ;

KREUTZMANN, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1986, 543 (12) :186-191

[6] A High-Performance Polymer Tin Sulfur Lithium Ion Battery [J].

Hassoun, Jusef ;

Scrosati, Bruno .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (13) :2371-2374

[7]

Heeger A.J., 2001, Angew. Chem, V113, P2660

[8]

Heeger AJ, 2001, ANGEW CHEM INT EDIT, V40, P2591, DOI 10.1002/1521-3773(20010716)40:14<2591::AID-ANIE2591>3.0.CO

[9]

2-0

[10]

Hesse M., 2005, SPEKTROSKOPISCHE MET

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