Anthracenylporphyrins

被引：16

作者：

Davis, Mia ^{[1
]}

Senge, Mathias O. ^{[1
]}

Locos, Oliver B. ^{[1
]}

机构：

[1] Trinity Coll Dublin, SFI Tetrapyrrole Lab, Sch Chem, Dublin 2, Ireland

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2010年 / 65卷 / 12期

基金：

爱尔兰科学基金会;

关键词：

Porphyrins; Conformational Analysis; Anthracenylporphyrins; Tetrapyrroles; Suzuki Coupling; CROSS-COUPLING REACTIONS; NUCLEOPHILIC-SUBSTITUTION; 2-PHOTON ABSORPTION; CRYSTAL-STRUCTURE; PORPHYRINS; DIPYRROMETHANES; PLANAR;

D O I：

10.1515/znb-2010-1211

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis and characterization of meso-anthracenylporphyrins with zinc and nickel metal centers. A variety of novel aryl and alkyl meso-substituted anthracenylporphyrins were synthesized via step-wise Suzuki cross-coupling reactions using anthracenyl boronates. This method was compared to standard syntheses based on condensation reactions to yield anthracenylporphyrins of the A(2)B(2)- and A(3) B-type. The work was complemented by the synthesis of a number of the functionalized anthracene derivatives via Suzuki couplings. Selected systems were subjected to single-crystal X-ray analysis which revealed an unusual close packing for nickel(II) anthracenylporphyrins.

引用

页码：1472 / 1484

页数：13

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