Rheological properties of nanopowder alumina coated with adsorbed fatty acids

The rheological properties of a nanosized alumina powder coated with fatty acid steric stabilizers of varying chain length were investigated. The storage and loss moduli of the complex modulus were measured to characterize the behavior of the flocculated systems. As chain length increased, there was a transition from an elastic response to fluid behavior. However, the fluid system developed elastic characteristics at relatively low volume fractions of 22%. The length of the steric barrier required to produce the fluid dispersion was estimated to be similar to 2 nm and correlates with attractive interactions on the order of the system thermal energy. Moreover, in the flocculated systems, the storage modulus was found to be higher than reported previously in the literature. These higher values were related to the additional attractive forces due to van der Waals attractions between the hydrocarbon tails of the adsorbed fatty acid layers. (c) 2005 Elsevier Inc. All rights reserved.