Hierarchical order in hollow spheres of mesoporous silicates

被引:159
作者
Lin, HP [1 ]
Cheng, YR [1 ]
Mou, CY [1 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
关键词
D O I
10.1021/cm980493v
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mesoporous MCM-41 silica hierarchical structures consisting of a high yield (similar to 98%) of uniform-sized hollow spheres of diameter 5.0 +/- 1.0 mu m have been obtained. The nanochannels on the shell are in latitude direction and the inside of the micron spheres has intricate pillar structures producing structures of various topological genus ranks.
引用
收藏
页码:3772 / +
页数:6
相关论文
共 26 条
  • [1] Biomimetic pathways for assembling inorganic thin films
    Aksay, IA
    Trau, M
    Manne, S
    Honma, I
    Yao, N
    Zhou, L
    Fenter, P
    Eisenberger, PM
    Gruner, SM
    [J]. SCIENCE, 1996, 273 (5277) : 892 - 898
  • [2] A PHASE OF LIPOSOMES WITH ENTANGLED TUBULAR VESICLES
    CHIRUVOLU, S
    WARRINER, HE
    NARANJO, E
    IDZIAK, SHJ
    RADLER, JO
    PLANO, RJ
    ZASADZINSKI, JA
    SAFINYA, CR
    [J]. SCIENCE, 1994, 266 (5188) : 1222 - 1225
  • [3] Bacterial templating of ordered macrostructures in silica and silica-surfactant mesophases
    Davis, SA
    Burkett, SL
    Mendelson, NH
    Mann, S
    [J]. NATURE, 1997, 385 (6615) : 420 - 423
  • [4] Morphology definition by disclinations and dislocations in a mesostructured silicate crystal (vol 71, pg 620, 1997)
    Feng, J
    Huo, Q
    Petroff, PM
    Stucky, GD
    [J]. APPLIED PHYSICS LETTERS, 1997, 71 (13) : 1887 - 1889
  • [5] INFLUENCE OF THE NATURE OF THE COUNTERION AND OF HEXANOL ON THE PHASE-BEHAVIOR OF THE DILUTE TERNARY-SYSTEMS - CETYLPYRIDINIUM BROMIDE OR CHLORIDE HEXANOL BRINE
    GOMATI, R
    APPELL, J
    BASSEREAU, P
    MARIGNAN, J
    PORTE, G
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (24) : 6203 - 6210
  • [6] HELFRICH W, 1978, Z NATURFORSCH A, V33, P305
  • [7] Two- and three-dimensional crystallization of polymeric microspheres by micromolding in capillaries
    Kim, E
    Xia, YN
    Whitesides, GM
    [J]. ADVANCED MATERIALS, 1996, 8 (03) : 245 - &
  • [8] EXTREME SWELLING OF A LYOTROPIC LAMELLAR LIQUID-CRYSTAL
    LARCHE, FC
    APPELL, J
    PORTE, G
    BASSEREAU, P
    MARIGNAN, J
    [J]. PHYSICAL REVIEW LETTERS, 1986, 56 (16) : 1700 - 1703
  • [9] Effect of delayed neutralization on the synthesis of mesoporous MCM-41 molecular sieves
    Lin, HP
    Cheng, SF
    Mou, CY
    [J]. MICROPOROUS MATERIALS, 1997, 10 (1-3): : 111 - 121
  • [10] Sol-gel synthesis of organized matter
    Mann, S
    Burkett, SL
    Davis, SA
    Fowler, CE
    Mendelson, NH
    Sims, SD
    Walsh, D
    Whilton, NT
    [J]. CHEMISTRY OF MATERIALS, 1997, 9 (11) : 2300 - 2310