Metallocene catalysts for olefin polymerization - Annual review for 1996

被引：133

作者：

Hlatky, GG ^{[1
]}

机构：

[1] Equistar Chem LP, Equistar Technol Ctr, Cincinnati, OH 45249 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 181卷

关键词：

metallocene catalysts; olefin polymerization; cyclopentadienyl rings;

D O I：

10.1016/S0010-8545(98)00220-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review covers research in olefin polymerization by metallocene catalysts published in 1996. While metallocenes are generally defined as metal complexes with two cyclopentadienyl rings, this review will additionally cover catalysts containing only one cyclopentadienyl ring, as well as catalysts with ligands isolobal to cyclopentadienide. Included will be certain disclosures concerning cocatalyst preparation and use. Polymer properties and uses will not be covered. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：243 / 296

页数：54

共 265 条

[1] Synthesis of hydroxyl group containing polyolefins with metallocene/methylaluminoxane catalysts [J].

Aaltonen, P ;

Fink, G ;

Lofgren, B ;

Seppala, J .

MACROMOLECULES, 1996, 29 (16) :5255-5260

[2]

AALTONEN P, 1996, Patent No. 34023

[3]

ABE Y, 1996, Patent No. 729983

[4]

Abe Y., US Patent, Patent No. 5650471

[5]

AGAPOIU AK, 1996, Patent No. 11960

[6]

AIDA F, 1996, Patent No. 714920

[7] C-2-symmetric bis(fluorenyl) complexes: Four complex models as potential catalysts for the isospecific polymerization of propylene [J].

Alt, HG ;

Zenk, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 512 (1-2) :51-60

[8] Syndio-specific polymerization of propylene: 3-, 4-, 3,4- and 4,5-substituted zirconocene complexes of type (C(13)H(8-n)R(n)CR(2)'C5H4)ZrCl2 (n=1, 2; R equals alkyl, aryl; R'=Me, Ph) [J].

Alt, HG ;

Zenk, R ;

Milius, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 514 (1-2) :257-270

[9] Syndiospecific polymerization of propylene: New metallocene complexes of the type (C(13)H(8-n)R(n)CR'R''C5H4)MCl(2) (n=0, 2; R=alkyl, aryl, hal; R', R''=H, alkyl, aryl; M=Zr, Hf) with respect to various bridge substituents [J].

Alt, HG ;

Zenk, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 518 (1-2) :7-15

[10] Syndiospecific polymerization of propylene: 2-substituted and 2,7-substituted metallocene complex of the (C(13)H(8-n)R(n)CR(n)(')C5H4)MCl(2) (n=1,2; R=alkoxy, alkyl, hal; R(')=Me, Ph; M=Zr, Hf) [J].

Alt, HG ;

Zenk, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (01) :39-54

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