Partial tetrahedral oxygen coordination of indium in BaIn2Zn3O7.: A consideration of the Ba2Ln2Zn8O13/BaLnAlZn3O7 type

被引：6

作者：

Sfreddo, O ^{[1
]}

Müller-Buschbaum, H ^{[1
]}

机构：

[1] Univ Kiel, Inst Anorgan Chem, D-24098 Kiel, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1998年 / 53卷 / 5-6期

关键词：

barium; indium; zinc; oxide; crystal structure;

D O I：

10.1515/znb-1998-5-603

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of BaIn2Zn3O7 have been prepared by solid state reaction and crystallization from flux. X-ray investigations led to hexagonal symmetry, space group C-6v(4)-P6(3)mc, lattice constants a = 6.342(1), c = 10.282(1) Angstrom, Z = 2. BaIn2Zn3O7 shows tetrahedral positions statistically occupied by In3+ and Zn2+. The crystal structure is isotypic to Ba(2)Ln(2)Zn(8)O(13) and BaLnAlZn(3)O(7). A discussion of the related compounds is given.

引用

页码：517 / 520

页数：4

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