π-conjugated oligo-(p-phenylenevinylene) rosettes and their tubular self-assembly

被引:180
作者
Jonkheijm, P
Miura, A
Zdanowska, M
Hoeben, FJM
De Feyter, S
Schenning, APHJ
De Schryver, FC
Meijer, EW
机构
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
[2] Katholieke Univ Leuven, Dept Chem, Lab Photochem & Spect, B-3001 Louvain, Belgium
关键词
helices; hydrogen bonds; noncovalent interactions; self-assembly; supramolecular chemistry;
D O I
10.1002/anie.200352790
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hierarchical self-assembly: Oligo(p-phenylenevinylene)s with pendant diamino triazine moieties can self-assemble through hydrogen-bonding interactions to give hexameric rosettes (see picture, left). These rosettes further organize into large supramolecular tubules (right) with perfect space filling.
引用
收藏
页码:74 / 78
页数:5
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