Chromium imine and amine complexes as homogeneous catalysts for the trimerisation and polymerisation of ethylene

被引：68

作者：

Bluhm, ME ^{[1
]}

Walter, O ^{[1
]}

Döring, M ^{[1
]}

机构：

[1] Forschungszentrum Karlsruhe, Inst Tech Chem, CPV, D-76021 Karlsruhe, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 03期

关键词：

trimerisation; polymerisation; single-site catalysts; ethylene; chromium;

D O I：

10.1016/j.jorganchem.2004.09.080

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cr(III) complexes of tridendate imine and amine ligands with N, P, O, S donor atoms 1 and 2 have been prepared and tested as catalysts in the oligomerisation and polymerisation of ethylene giving excellent selectivity towards 1-hexene and polymerisation to polyethylene when activated with cocatalysts. X-ray structure analyses of the precatalysts 1a-c, 1i, and 2b are investigated. The metal-ligand binding in 1a and 1b is nearly the same, which leads to similar catalytic activities of these precatalysts. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：713 / 721

页数：9

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