Wadsworth-Emmons reactions catalyzed by nanocrystalline MgO

被引:22
作者
Choudary, BM [1 ]
Mahendar, K [1 ]
Ranganath, KVS [1 ]
机构
[1] Indian Inst Chem Technol, Inorgan Chem Div, Hyderabad 500007, Andhra Pradesh, India
关键词
phosphonate; nanocrystalline; Wadsworth-Emmons; MgO;
D O I
10.1016/j.molcata.2005.02.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Wadsworth-Emmons reactions between different aldehydes including aliphatic, aromatic, cyclic and heterocyclic with various phosphonates affords alpha,beta-unsaturated nitriles and esters under mild conditions without the formation of by-products such as Michael or Knoevenagel products using a nanocrystalline MgO catalyst. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:25 / 27
页数:3
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