Three metal (1,4,8,11-tetraazacyclotetradeeane) halide salts

被引：19

作者：

Chen, X ^{[1
]}

Long, G ^{[1
]}

Willet, RD ^{[1
]}

Hawks, T ^{[1
]}

Molnar, S ^{[1
]}

Brewer, K ^{[1
]}

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195016829

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Attempts to synthesize [M([14]aneN(4))[M'X(4)] chain systems (M,M' = divalent metal ion, [14]aneN(4) = 1,4,8,11-tetraazacyclotetradecane, X = Cl, Br) yeilded three M([14]aneN(4))X(2).xH(2)O salts. The structures of these three salts, dibromo(1,4,8,11-tetraazacyclotetradecane-N,N',N '',Ntriple prime)copper(II), [CuBr2(C10H24N4)], dichloro(1,4,8,11-tetraazacyclotetradecane-N,N',N '',Ntriple prime )manganese(II)-dichloro(1,4,8,11-tetraazacyclotetradecane-N,- N',N '',Ntriple prime)nickel(II)-water (0.66/0.34/6), [Mn0.66Ni0.34-Cl-2(C10H24N4)].6H(2)O, and dichloro(1,4,8,11-tetraazacyclotetradecane-N,N',N '',Ntriple prime)cobalt(III)-dichloro(1,4,- 8,11-tetraazacyclotetradecane-N, N',N '', Ntriple prime)manganese-(II)-chloride-water 0.5/0.5/0.5/5.5), [Co0.5Mn0.5Cl2-(C10H24N4)]Cl-0.5.5.5H(2)O are described.

引用

页码：1924 / 1928

页数：5

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