Synthesis and characterization of a pillared clay membrane

被引:20
作者
Vercauteren, S [1 ]
Luyten, J [1 ]
Leysen, R [1 ]
Vansant, EF [1 ]
机构
[1] VLAAMSE INSTELLING TECHNOL ONDERZOEK, DIV MAT, B-2400 MOL, BELGIUM
关键词
pillared clay membranes; gas separation; Al2O3-pillared montmorillonite; membrane preparation;
D O I
10.1016/0376-7388(96)00147-0
中图分类号
TQ [化学工业];
学科分类号
0817 [化学工程与技术];
摘要
Ceramic multilayer membranes with a top layer of Al2O3-pillared montmorillonite were prepared. To deposit the top layer, a gamma-alumina membrane was first dipped in a montmorillonite suspension followed by a pillaring of the deposited clay layer. SEM analysis showed that very thin top layers were formed. The layer thickness increased with dipping time but could be limited to a few tenths of a micrometer. Although the top layer was very thin, gas permeation measurements indicated a high flow resistance. X-ray diffraction indicated that the low permeation was possibly due to an incomplete pillaring of the clay layer.
引用
收藏
页码:161 / 168
页数:8
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