Quasi-chemical studies of ordering in the Cu-Zr and Cu-Si melts

被引：12

作者：

Anusionwu, BC

Adebayo, GA

机构：

[1] Abdus Salam Int Ctr Theoret Phys, Trieste, Italy

[2] Inst Theoret Phys, D-14195 Berlin, Germany

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2001年 / 329卷 / 1-2期

关键词：

liquid alloys; thermodynamic modelling; enthalpy; entropy;

D O I：

10.1016/S0925-8388(01)01572-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The quasi chemical approximation (QCA) for strongly interacting systems has been applied to study ordering and glass formation tendencies in metal-metal and metal-nonmetal liquid alloy systems; in this case Cu-Zr and Cu-Si at temperatures of about 1499 and 1599 K, respectively. While the QCA results show good agreement with experimental thermodynamic data for Cu-Zr which manifested high tendency to glass formation at Zr concentrations greater than 0.6 atomic fractions, the agreement of the QCA results with experimental thermodynamic data for Cu-Si were not in good agreement suggesting some limitations to the QCA formulations. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：162 / 167

页数：6

共 20 条

[1] A THEORETICAL-STUDY OF ORDERING PHENOMENA IN K-IN AND K-SB MOLTEN ALLOYS [J].