Polyazolyl chelate chemistry. 12. An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand

被引：112

作者：

Foreman, MRSJ ^{[1
]}

Hill, AF

Owen, GR

White, AJP

Williams, DJ

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Australian Natl Univ, Res Sch Chem, Inst Adv Studies, Canberra, ACT, Australia

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 22期

关键词：

D O I：

10.1021/om030550g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [RuHCl(CO)(PPh3)(3)] or [RuH(NCMe)(2)(CO)(PPh3)(2)] ClO4 with Na[HB(mt)(3)] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){kappa(3)-H,S,S"-HB(mt)(3)}], which hydrogenates ethynylbenzene to styrene with formation of the ruthenaboratrane [Ru(CO)(PPh3){B(mt)(3)}](Ru-->B).

引用

页码：4446 / 4450

页数：5

共 44 条

[11] COMPLEXES WITH UNBRIDGED DATIVE BONDS BETWEEN OSMIUM AND A GROUP-6 ELEMENT - STRUCTURES OF (ME3P)(OC)4OSCR, (ME3P)(OC)4OSW(CO)5 [J].

DAVIS, HB ;

EINSTEIN, FWB ;

GLAVINA, PG ;

JONES, T ;

POMEROY, RK ;

RUSHMAN, P .

ORGANOMETALLICS, 1989, 8 (04) :1030-1039

[12] PREPARATION AND CRYSTAL-STRUCTURE OF (OC)5OSOS(CO)3(GECL3)(CL) - A COMPOUND WITH AN UNSUPPORTED, DONOR-ACCEPTOR METAL METAL BOND [J].

EINSTEIN, FWB ;

POMEROY, RK ;

RUSHMAN, P ;

WILLIS, AC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (15) :854-855

[13] COMPARISON OF DATIVE AND COVALENT METAL METAL BONDS - STRUCTURES OF THE ISOMERS (ME3P)(OC)4OSRE(CO)4(BR) AND (BR)(ME3P)(OC)3OSRE(CO)5 [J].

EINSTEIN, FWB ;

JENNINGS, MC ;

KRENTZ, R ;

POMEROY, RK ;

RUSHMAN, P ;

WILLIS, AC .

INORGANIC CHEMISTRY, 1987, 26 (08) :1341-1344

[14] The chemical and catalytic reactions of hydrido-chloro-carbonylbis (triisopropylphosphine)osmium(II) and its major derivatives [J].

Esteruelas, MA ;

Oro, LA .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 47, 2001, 47 :1-59

[15] Re and Tc complexes containing B-H•••M agostic interactions as building blocks for the design of radiopharmaceuticals [J].

Garcia, R ;

Paulo, A ;

Domingos, A ;

Santos, I ;

Ortner, K ;

Alberto, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (45) :11240-11241

[16] Rhenium(I) organometallic complexes with novel bis(mercaptoimidazolyl)borates and with hydrotris(mercaptoimidazolyl)borate: chemical and structural studies [J].

Garcia, R ;

Paulo, A ;

Domingos, K ;

Santos, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 632 (1-2) :41-48

[17] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CABYNE LIGANDS .52. SYNTHESIS AND REACTIONS OF THE COMPOUNDS [RUW(MU-CR)-(CO)3(ETA-C5H5)(ETA-5-C2B9H9ME2)] (R = C6H4ME-4 OR ME) - CRYSTAL-STRUCTURES OF [RUW(MU-CC6H4ME-4)(CO)3(ETA-C5H5)(ETA-5-C2B9H9ME2)] AND [N(PPH3)2][RUW(MU-CC6H4ME-4)(MU-SIGMA,ETA-5-C2B9H8ME2)(CO)3(ETA-C5H5)]( [J].

GREEN, M ;

HOWARD, JAK ;

JELFS, AND ;

JOHNSON, O ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (01) :73-79

[18] ORGANOMETALLIC MACROCYCLE CHEMISTRY .4. SYNTHESIS AND REACTIONS OF [RUX(CS)(PPH(3))([9]ANES(3))] CLO4 (X=H, CL, SCN, SC(6)H(4)ME-4 - [9]ANES(3)=1,4,7-TRITHIACYCLONONANE) [J].

HECTOR, AL ;

HILL, AF .

INORGANIC CHEMISTRY, 1995, 34 (14) :3797-3800

[19]

Hill AF, 1999, ANGEW CHEM INT EDIT, V38, P2759, DOI 10.1002/(SICI)1521-3773(19990917)38:18&lt

[20]

2759::AID-ANIE2759&gt

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