Stereoselective cis-addition of aromatic C-H bonds to alkynes catalyzed by dinuclear palladium complexes

被引：115

作者：

Tsukada, N ^{[1
]}

Mitsuboshi, T ^{[1
]}

Setoguchi, H ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Chem Mat, Sendai, Miyagi 9808579, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 40期

关键词：

D O I：

10.1021/ja0375075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of alkynes with arenes proceeded in the presence of dinuclear palladium complexes and trialkylboranes to yield alkyne hydroarylation products with high stereoselectivity. In the reactions of monosubstituted benzenes, meta and para products were formed in statistical ratios, while no ortho isomers were detected. Copyright © 2003 American Chemical Society.

引用

页码：12102 / 12103

页数：2

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