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Oxygen transport through LSM/YSZ/LaAlO system for use of fuel cell type reactor

被引：26
作者：
Kiatkittipong, W
Tagawa, T [1 ]
Goto, S
Assabumrungrat, S
Praserthdam, P
机构：
[1] Nagoya Univ, Dept Chem Engn, Nagoya, Aichi 4648603, Japan
[2] Chulalongkorn Univ, Dept Chem Engn, Ctr Excellence Catalysis & Catalyt React Engn, Bangkok 10330, Thailand
来源：
CHEMICAL ENGINEERING JOURNAL | 2005年 / 106卷 / 01期
关键词：
solid oxide fuel cell; SOFC reactor; oxygen permeation; modeling; methane;
D O I：
10.1016/j.cej.2004.11.004
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Oxygen transport in an LSM/YSZ/LaAlO solid oxide fuel cell type reactor was studied. The oxygen permeation flux was 8.90 x 10(-8) mol m(-2) s(-1) at 1173K with an activation energy of 170 kJmol(-1). By applying an external potential, the oxygen permeation flux increased while the activation energy of oxygen permeation decreased. The oxygen permeation fluxes under methane feed in the anode side are 1-2 orders of magnitude higher than those under helium feed. A model of oxygen permeation was presented and the permeation parameters were proposed. In the case of helium feed, the oxygen permeation at the LaAlO anode was the rate-limiting step. However, changing helium to methane as a reactive gas, the resistances for the oxygen permeation in the three parts (LSM/YSZ/LaAlO) were comparable. (C) 2004 Elsevier B.V. All rights reserved.
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页码：35 / 42
页数：8
相关论文
共 26 条
[1]   Comparative study on oxygen permeation and oxidative coupling of methane on disk-shaped and tubular dense ceramic membrane reactors [J].
Akin, FT ;
Lin, YS ;
Zeng, Y .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (25) :5908-5916
[2]   ZIRCONIA-BASED SOLID ELECTROLYTES - MICROSTRUCTURE, STABILITY AND IONIC-CONDUCTIVITY [J].
BADWAL, SPS .
SOLID STATE IONICS, 1992, 52 (1-3) :23-32
[3]   Application of mist pyrolysis method to preparation of Ni/ZrO2 anode catalyst for SOFC type reactor [J].
Carrillo, AS ;
Tagawa, T ;
Goto, S .
MATERIALS RESEARCH BULLETIN, 2001, 36 (5-6) :1017-1027
[4]   Simulation of membrane microreactor for fuel cell with methane feed [J].
Goto, S ;
Tagawa, T ;
Assabumrungrat, S ;
Praserthdam, P .
CATALYSIS TODAY, 2003, 82 (1-4) :223-232
[5]   Oxygen permeation through thin zirconia/yttria membranes prepared by EVD [J].
Han, JH ;
Xomeritakis, G ;
Lin, YS .
SOLID STATE IONICS, 1997, 93 (3-4) :263-272
[6]   Fe doped LaGaO3 perovskite oxide as an oxygen separating membrane for CH4 partial oxidation [J].
Ishihara, T ;
Tsuruta, Y ;
Todaka, T ;
Nishiguchi, H ;
Takita, Y .
SOLID STATE IONICS, 2002, 152 :709-714
[7]   Faradaic efficiency and oxygen permeability of Sr0.97Ti0.60Fe0.40O3-δ perovskite [J].
Kharton, VV ;
Kovalevsky, AV ;
Viskup, AP ;
Figueiredo, FM ;
Frade, JR ;
Yaremchenko, AA ;
Naumovich, EN .
SOLID STATE IONICS, 2000, 128 (1-4) :117-130
[8]   Oxygen permeability of perovskite-typeSr0.7Ce0.3MnO3-δ [J].
Kharton, VV ;
Viskup, AP ;
Marozau, IP ;
Naumovich, EN .
MATERIALS LETTERS, 2003, 57 (20) :3017-3021
[9]   TPD study in LSM/YSZ/LaAlO system for the use of fuel cell type reactor [J].
Kiatkittipong, W ;
Tagawa, T ;
Goto, S ;
Assabumrungrat, S ;
Praserthdam, P .
SOLID STATE IONICS, 2004, 166 (1-2) :127-136
[10]   Oxygen-permeating property of LaSrBFeO3 (B=Co, Ga) perovskite membrane surface-modified by LaSrCoO3 [J].
Lee, S ;
Lee, KS ;
Woo, SK ;
Kim, JW ;
Ishihara, T ;
Kim, DK .
SOLID STATE IONICS, 2003, 158 (3-4) :287-296
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