Hofmeister series:: The hydrolytic activity of Aspergillus niger lipase depends on specific anion effects

被引：87

作者：

Pinna, MC

Salis, A

Monduzzi, M

Ninham, BW

机构：

[1] Univ Cagliari, Dipartimento Sci Chim, I-09042 Monserrato, Italy

[2] Australian Natl Univ, Dept Appl Math, Canberra, ACT, Australia

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2005年 / 109卷 / 12期

关键词：

D O I：

10.1021/jp050574w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The specific activity of lipase A (Aspergillus niger) toward the hydrolysis of p-nitrophenyt acetate (p-NPA) is shown to increase as a result of sodium salt addition according to specific ion effects of the Hofmeister series. This shows explicitly that the Hofmeister effect is due to the different specific interactions between anions and the enzymatic surface.

引用

页码：5406 / 5408

页数：3

共 23 条

[1] Hofmeister effect on enzymatic catalysis and colloidal structures [J].

Bauduin, P ;

Renoncourt, A ;

Touraud, D ;

Kunz, W ;

Ninham, BW .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2004, 9 (1-2) :43-47

[2] Composition and activity of commercial triacylglycerol acylhydrolase preparations [J].

Bjurlin, MA ;

Bloomer, S ;

Haas, MJ .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2001, 78 (02) :153-160

[3] Why the properties of proteins in salt solutions follow a Hofmeister series [J].

Boström, M ;

Williams, DRM ;

Ninham, BW .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2004, 9 (1-2) :48-52

[4] Specific ion effects:: Why DLVO theory fails for biology and colloid systems -: art. no. 168103 [J].

Boström, M ;

Williams, DRM ;

Ninham, BW .

PHYSICAL REVIEW LETTERS, 2001, 87 (16) :168103/1-168103/4

[5] THE HOFMEISTER EFFECT AND THE BEHAVIOR OF WATER AT INTERFACES [J].

COLLINS, KD ;

WASHABAUGH, MW .

QUARTERLY REVIEWS OF BIOPHYSICS, 1985, 18 (04) :323-422

[6] STICKY IONS IN BIOLOGICAL-SYSTEMS [J].

COLLINS, KD .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1995, 92 (12) :5553-5557

[7] Charge density-dependent strength of hydration and biological structure [J].

Collins, KD .

BIOPHYSICAL JOURNAL, 1997, 72 (01) :65-76

[8] On the mechanism of the Hofmeister effect [J].

Gurau, MC ;

Lim, SM ;

Castellana, ET ;

Albertorio, F ;

Kataoka, S ;

Cremer, PS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (34) :10522-10523

[9]

Hofmeister F., 1888, Archiv for Experimentelle Pathologie und Pharmakologie, V24, P247, DOI [10.1007/BF01918191, DOI 10.1007/BF01918191, 10.1007/bf01918191]

[10] How ions affect the structure of water [J].

Hribar, B ;

Southall, NT ;

Vlachy, V ;

Dill, KA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (41) :12302-12311

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