A novel monomeric tin(II) phosphate, [N(C2H5NH3)3]3+ [Sn(PO4) (HPO4)]3-•4H2O, connected through hydrogen bonding

被引：43

作者：

Ayyappan, S

Cheetham, AK ^{[1
]}

Natarajan, S

Rao, CNR

机构：

[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[2] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1998年 / 139卷 / 01期

关键词：

D O I：

10.1006/jssc.1998.7897

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tin(II) phosphate, [N(C2H5NH3)(3)](3+) [Sn(PO4)(HPO4)](3-) 4H(2)O, contains monomeric Sn-2(PO4)(2)(HPO4)(2) units which form a hydrogen-bonded network with the TREN amine (TREN = N(C2H5NH3)(3)(3+)); triclinic, space group P1 (no. 2), a = 9.579(1), b = 10.507(1), c = 10.976(1) Angstrom; alpha = 72.93(1)degrees, beta = 78.03(1)degrees, gamma = 69.82(1)degrees, V = 984.2(1) Angstrom(3), Z = 2, The Sn2P2O4 core of this unit is a common structural feature of open-framework tin phosphates and may play a role as a building block for this class of materials. (C) 1998 Academic Press.

引用

页码：207 / 210

页数：4

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