Intermolecular forces in an ionic liquid ([Mmim][Cl]) versus those in a typical salt (NaCl)

被引：155

作者：

Zahn, Stefan ^{[1
]}

Uhlig, Frank ^{[1
]}

Thar, Jens ^{[1
]}

Spickermann, Christian ^{[1
]}

Kirchner, Barbara ^{[1
]}

机构：

[1] Univ Leipzig, Wilhelm Ostwald Inst Phys & Theoret Chem, D-04103 Leipzig, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 19期

关键词：

ab initio calculations; intermolecular forces; ionic liquids; perturbation theory;

D O I：

10.1002/anie.200705526

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) A subtle difference: In ionic liquids the "weak" dispersion forces have a significant impact on the shape of the potential energy surface, which results in a shallow profile when all of the contributions are considered. Such findings are commonly accepted to determine the liquid state. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3639 / 3641

页数：3

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