Parallel and inclined (1D→2D) interlacing modes in new polyrotaxane frameworks [M2(bix)3(SO4)2] [M = Zn(II), Cd(II);: Bix=1,4-bis(imidazol-1-ylmethyl)benzene]

被引：121

作者：

Carlucci, L ^{[1
]}

Ciani, G ^{[1
]}

Proserpio, DM ^{[1
]}

机构：

[1] Dipartimento Chim Strutturale & Stereochim Inorga, Via G Venezian 21, I-20133 Milan, Italy

来源：

CRYSTAL GROWTH & DESIGN | 2005年 / 5卷 / 01期

关键词：

D O I：

10.1021/cg049794+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of M-II sulfates (M = Zn, Cd) with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) yield the novel interesting coordination networks [M-2(bix)(3)(SO4)(2)], containing 1D polymeric motifs of alternating rings and rods, which show extended rotaxane-like mechanical links producing 2D sheets via unprecedented parallel (M = Zn) or inclined (M = Cd) interlacing modes of the chains.

引用

页码：37 / 39

页数：3

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