Preparation of binary conductive polymer composites with very low percolation threshold by latex blending

被引:53
作者
Hu, JW [1 ]
Li, MW
Zhang, MQ
Xiao, DS
Cheng, GS
Rong, MZ
机构
[1] Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Peoples R China
[2] Zhongshan Univ, Minist Educ, Key Lab Polymer Composite & Funct Mat, Guangzhou 510275, Peoples R China
关键词
blending; carbon black; composites; percolation; polyurethanes;
D O I
10.1002/marc.200300014
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The communication reports a way to prepare carbon black (CB)/waterborne polyurethane conducting composites with percolation thresholds as low as 0.2 vol.% through conventional latex blending. CB particles in the composites appear segregated in their distribution and are located in the two-dimensional interstices among the polymer domains. The intimate filler/matrix interaction also improves the tensile strength of the matrix at the CB content corresponding to the electrical percolation threshold.
引用
收藏
页码:889 / 893
页数:5
相关论文
共 22 条
[1]   FORMATION OF FILMS FROM POLYMER DISPERSIONS [J].
BROWN, GL .
JOURNAL OF POLYMER SCIENCE, 1956, 22 (102) :423-434
[2]   Effect of dispersing aid on electrical and mechanical behavior of carbon black-filled latex [J].
Grunlan, JC ;
Bloom, FL ;
Gerberich, WW ;
Francis, LF .
JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (16) :1523-1526
[3]  
Grunlan JC, 2001, J APPL POLYM SCI, V80, P692, DOI 10.1002/1097-4628(20010425)80:4<692::AID-APP1146>3.3.CO
[4]  
2-N
[5]   SELECTIVE LOCALIZATION OF CARBON-BLACK IN IMMISCIBLE POLYMER BLENDS - A USEFUL TOOL TO DESIGN ELECTRICAL CONDUCTIVE COMPOSITES [J].
GUBBELS, F ;
JEROME, R ;
TEYSSIE, P ;
VANLATHEM, E ;
DELTOUR, R ;
CALDERONE, A ;
PARENTE, V ;
BREDAS, JL .
MACROMOLECULES, 1994, 27 (07) :1972-1974
[6]  
HALL DE, 1991, INT ENCY COMPOSITES, P469
[7]  
Kendall K, 1982, INT J ADHES ADHES, V2, P149
[8]   PERCOLATION AND CONDUCTION [J].
KIRKPATRICK, S .
REVIEWS OF MODERN PHYSICS, 1973, 45 (04) :574-588
[9]  
KLASON C, 1975, J APPL POLYM SCI, V19, P8315
[10]   POLY(VINYL ACETATE) SILICA FILLED MATERIALS - MATERIAL PROPERTIES OF IN-SITU VS FUMED SILICA PARTICLES [J].
LANDRY, CJT ;
COLTRAIN, BK ;
LANDRY, MR ;
FITZGERALD, JJ ;
LONG, VK .
MACROMOLECULES, 1993, 26 (14) :3702-3712