Insertion of a water oxygen atom into a phosphorus-metal bond:: From a P-coordinated (diphenylphosphino)alkyne to a coordinated η2(O,C)-vinyldiphenylphosphine oxide

被引：7

作者：

Louattani, E

Moldes, I

Suades, J

Piniella, JF

Alvarez-Larena, A

机构：

[1] Univ Autonoma Barcelona, Dept Quim, Bellaterra 08193, Spain

[2] Univ Autonoma Barcelona, Dept Geol, Bellaterra 08193, Spain

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 15期

关键词：

D O I：

10.1021/om9801610

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [(Fp)Ph2PC=CR][BF4] (Fp = (C5H5)Fe(CO)(2); R = H (1), Me (2), tBu (3), Ph (4), Tol (5)) with (CH3)(3)NO . 2H(2)O. (6) was studied, and the new complexes [CpFe(CO)(eta(2)(O,C)-Ph2P(O)CH=CR)] (R = Ph (7), Tol (8)) were isolated. Compound 8 was characterized by X-ray diffraction. An isotopic labeling study showed that the oxygen atom bonded to phosphorus came from a water molecule.

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页码：3394 / 3397

页数：4

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