Silylgermylpotassium compounds

被引：53

作者：

Fischer, J ^{[1
]}

Baumgartner, J ^{[1
]}

Marschner, C ^{[1
]}

机构：

[1] Graz Tech Univ, Inst Anorgan Chem, A-8010 Graz, Austria

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 06期

关键词：

D O I：

10.1021/om0491894

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By the reactions of potassium tert-butoxide with a number of oligosilylgermanes, oligosilylgermylpotassium compounds were generated. Their chemistry very much resembles that of the analogous oligosilylsilylpotassium compounds. However, the ease of formation is even more pronounced in the case of the germyl anions. Again potassium tert-butoxide proved to be a highly selective metalation reagent, leading to no unwanted cleavage of Si-Ge or Ge-Ge bonds. A number of new and potentially useful oligosilylgermyl mono- and dianions have been prepared in this manner.

引用

页码：1263 / 1268

页数：6

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