Magnetic field effects on emission and current in Alq3-based electroluminescent diodes

被引:305
作者
Kalinowski, J [1 ]
Cocchi, M [1 ]
Virgili, D [1 ]
Di Marco, P [1 ]
Fattori, V [1 ]
机构
[1] Gdansk Univ Technol, Dept Mol Phys, PL-80952 Gdansk, Poland
关键词
D O I
10.1016/j.cplett.2003.09.086
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The light output and the current driving tris-(8-hydroxyquinolinato) aluminum (III) (Alq(3))-based light-emitting-diodes were found to increase by up to 5% and 3%, respectively, as an external magnetic field increased to 300 mT. The positive magnetic-field effects were sensitive to the applied voltage. These observations made clear that the emissive singlet exciton formation proceeds via a correlated electron-hole pair state and the excitonic injection of electrons contributes to the driving current, the concentration of singlet excitons being modulated by the hyperfine scale magnetic-field-dependent mixing of singlet and triplet pair states constituting precursors of molecular excitons. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:710 / 715
页数:6
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