Design of an organic chromophore for p-type dye-sensitized solar cells

被引:351
作者
Qin, Peng
Zhu, Hongjun
Edvinsson, Tomas
Boschloo, Gerrit
Hagfeldt, Anders
Sun, Licheng
机构
[1] KTH Chem Sci & Engn, Ctr Mol Devices, Dept Chem, S-10044 Stockholm, Sweden
[2] Uppsala Univ, Dept Chem Mat, Angstrom Lab, S-75121 Uppsala, Sweden
[3] Dalian Univ Technol, KTH Joint Educ & Res Ctr Mol Devices, State Key Lab Fine Chem, Royal Inst Technol, Dalian 116012, Peoples R China
关键词
D O I
10.1021/ja8001474
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A successful model for the design of efficient dyes for p-type dye-sensitized solar cells (DSSCs) is presented. As an example, a novel and efficient organic dye containing a triphenylamine chromophore has been synthesized and successfully applied in a p-type DSSC. The highest incident photon-to-current conversion efficiency (IPCE) of 18% in the visible region has been obtained, which is the highest value so far in p-type DSSCs. This is remarkably high, considering that only 600 nm thin NiO mesoporous films were used as p-type DSSC electrodes.
引用
收藏
页码:8570 / +
页数:3
相关论文
共 14 条
[1]   Sensitized hole injection of phosphorus porphyrin into NiO:: Toward new photovoltaic devices [J].
Borgström, M ;
Blart, E ;
Boschloo, G ;
Mukhtar, E ;
Hagfeldt, A ;
Hammarström, L ;
Odobel, F .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (48) :22928-22934
[2]   Spectroelectrochemistry of nanostructured NiO [J].
Boschloo, G ;
Hagfeldt, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (15) :3039-3044
[3]   PHOTOELECTROCHEMICAL PROPERTIES OF RHODAMINE-C18 SENSITIZED P-CUSCN PHOTOELECTROCHEMICAL CELL (PEC) [J].
FERNANDO, CAN ;
KITAGAWA, A ;
SUZUKI, M ;
TAKAHASHI, K ;
KOMURA, T .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1994, 33 (03) :301-315
[4]  
Frisch M. J., 2016, J AM CHEM SOC, DOI DOI 10.1021/JA205566W
[5]   Molecular photovoltaics [J].
Hagfeldt, A ;
Grätzel, M .
ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) :269-277
[6]   Dye-sensitized nanostructured p-type nickel oxide film as a photocathode for a solar cell [J].
He, JJ ;
Lindström, H ;
Hagfeldt, A ;
Lindquist, SE .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (42) :8940-8943
[7]   Dye-sensitized nanostructured tandem cell-first demonstrated cell with a dye-sensitized photocathode [J].
He, JJ ;
Lindström, H ;
Hagfeldt, A ;
Lindquist, SE .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 62 (03) :265-273
[8]   ELECTROCHEMICAL INVESTIGATIONS ON SPECTRAL SENSITIZATION OF GALLIUM PHOSPHIDE ELECTRODES [J].
MEMMING, R ;
TRIBUTSC.H .
JOURNAL OF PHYSICAL CHEMISTRY, 1971, 75 (04) :562-&
[9]   Photoinduced ultrafast dynamics of coumarin 343 sensitized p-type-nanostructured NiO films [J].
Morandeira, A ;
Boschloo, G ;
Hagfeldt, A ;
Hammarström, L .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (41) :19403-19410
[10]   Improved photon-to-current conversion efficiency with a nanoporous p-type NiO electrode by the use of a sensitizer-acceptor dyad [J].
Morandeira, Ana ;
Fortage, Jerome ;
Edvinsson, Tomas ;
Le Pleux, Loic ;
Blart, Errol ;
Boschloo, Gerrit ;
Hagfeldt, Anders ;
Hanmiarstrom, Leif ;
Dobel, Fabrice .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (05) :1721-1728