Homoleptic Silver(I) acetylene complexes

被引：76

作者：

Reisinger, Andreas

Trapp, Nils

Krossing, Ingo

Altmannshofer, Sandra

Herz, Verena

Presnitz, Manuel

Scherer, Wolfgang

机构：

[1] Univ Freiburg, Inst Anorgan & Allgemeine Chem, D-79104 Freiburg, Germany

[2] Univ Augsburg, Inst Phys, D-86159 Augsburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 43期

关键词：

ab initio calculations; alkynes; charge density; silver; weakly coordinating anions;

D O I：

10.1002/anie.200702688

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Hanging on to acetylene: The solid-state structures of the first homoleptic metal HG≡CH complexes [M(C2H 2)x]n (M = any metal; n, x = any number), salts of [Ag(η2-C2H2)n]+ (n = 3,4), are described (see picture). The electronic structure of a [Ag(η2-C2H2)] model complex has been investigated by experimental charge-density studies. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8295 / 8298

页数：4

共 53 条

[1] Extending the coordination chemistry of molecular P4S3:: The polymeric Ag(P4S3)+ and Ag(P4S3)2+ cations [J].