An azide-bridged homospin single-chain magnet:: [Co(2,2′-bithiazoline)(N3)2]n

被引:493
作者
Liu, TF
Fu, D
Gao, S [1 ]
Zhang, YZ
Sun, HL
Su, G
Liu, YJ
机构
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth mat Chem & Applicat, Beijing 100871, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Dept Phys, Beijing 100039, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
关键词
D O I
10.1021/ja0380751
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2′-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5?6 K, typical of single-chain magnet behavior. Copyright © 2003 American Chemical Society.
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收藏
页码:13976 / 13977
页数:2
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