3D metal-organic frameworks based on elongated tetracarboxylate building blocks for hydrogen storage

被引：78

作者：

Ma, Liqing

Lee, Jeong Yong ^{[2
]}

Li, Jing ^{[2
]}

Lin, Wenbin ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

[2] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 10期

关键词：

D O I：

10.1021/ic8003855

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two 3D metal-organic frameworks (MOFs) with a new biphenol-derived tetracarboxylate linker and Cu-II and Zn-II metal-connecting points were synthesized and characterized by single-crystal X-ray crystallographic studies. The two isostructural MOFs exhibit distorted PtS network topology and show markedly different framework stability. The porosity and hydrogen uptake of the frameworks were determined by gas adsorption experiments.

引用

收藏

页码：3955 / 3957

页数：3

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