Miniemulsion polymerization

被引:381
作者
Schork, FJ [1 ]
Luo, YW
Smulders, W
Russum, JP
Butté, A
Fontenot, K
机构
[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
[2] Zhejiang Univ, Coll Mat & Chem Engn, State Key Lab Polymer React Engn, Hangzhou 310027, Peoples R China
[3] ETH Honggerberg, Inst Chem & Bioengn, ETH Zurich, Prof M Morbidelli Grp, CH-8093 Zurich, Switzerland
[4] Eastman Chem Co, Kingsport, TN 37662 USA
来源
POLYMER PARTICLES | 2005年 / 175卷
关键词
miniemulsion; polymerization; emulsion; free radical; colloid;
D O I
10.1007/b100115
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The subject of miniemulsion polymerization is reviewed. The approach taken is one that combines a review of the technology with historical and tutorial aspects. Rather than developing an absolutely exhaustive review, a tutorial approach has been taken, emphasizing the critical features and advantages of miniemulsion polymerization. In keeping with this tutorial approach, a discussion of conventional emulsion polymerization is included in order to be able to compare and contrast miniemulsion polymerization and conventional emulsion polymerization later in the review. Areas where miniemulsion polymerization has been adopted commercially, or where it is likely to be adopted are highlighted.
引用
收藏
页码:129 / 255
页数:127
相关论文
共 363 条
[1]   High solids content miniemulsion polymerization of vinyl acetate in a continuous stirred tank reactor [J].
Aizpurua, I ;
Amalvy, JI ;
de la Cal, JC ;
Barandiaran, MJ .
POLYMER, 2001, 42 (04) :1417-1427
[2]   Comparison between conventional emulsion and miniemulsion polymerization of vinyl acetate in a continuous stirred tank reactor [J].
Aizpurua, I ;
Barandiaran, MJ .
POLYMER, 1999, 40 (14) :4105-4115
[3]   Influence of the polymeric hydrophobe on the kinetics of vinyl acetate miniemulsion polymerization [J].
Aizpurua, I ;
Amalvy, JI ;
Barandiaran, MJ .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2000, 166 (1-3) :59-66
[4]   MOLECULAR-WEIGHT DISTRIBUTIONS IN THE MINIEMULSION POLYMERIZATION OF STYRENE INITIATED BY OIL-SOLUBLE INITIATORS [J].
ALDUNCIN, JA ;
ASUA, JM .
POLYMER, 1994, 35 (17) :3758-3765
[5]   MINIEMULSION POLYMERIZATION USING OIL-SOLUBLE INITIATORS [J].
ALDUNCIN, JA ;
FORCADA, J ;
ASUA, JM .
MACROMOLECULES, 1994, 27 (08) :2256-2261
[6]  
ALEXANDER AE, 1971, PROGR POLYMER SCIENC, V3, P145
[7]   Living radical polymerization of methyl methacrylate with ruthenium complex: Formation of polymers with controlled molecular weights and very narrow distributions [J].
Ando, T ;
Kato, M ;
Kamigaito, M ;
Sawamoto, M .
MACROMOLECULES, 1996, 29 (03) :1070-1072
[8]  
[Anonymous], 2000, CONTROLLEDLIVING RAD
[9]   Polyreactions in miniemulsions [J].
Antonietti, M ;
Landfester, K .
PROGRESS IN POLYMER SCIENCE, 2002, 27 (04) :689-757
[10]  
ANTONIETTI M, 2002, CHEM-ING-TECH, V74, P543