Electron localization in poly(alkoxyanilines)

被引：12

作者：

Raghunathan, A

Kahol, PK ^{[1
]}

McCormick, BJ

机构：

[1] Wichita State Univ, Dept Phys, Wichita, KS 67260 USA

[2] Wichita State Univ, Dept Chem, Wichita, KS 67260 USA

来源：

SOLID STATE COMMUNICATIONS | 1998年 / 108卷 / 11期

基金：

美国国家科学基金会;

关键词：

polymers; electronic transport;

D O I：

10.1016/S0038-1098(98)00452-9

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Electrical conductivity, magnetic susceptibility and electron spin resonance results are reported in poly(o-methoxyaniline), poly(o-ethoxyaniline) and an equimolar blend of polyaniline and poly(o-methoxyaniline) for different protonic acids. Electron localization length is found to be much larger in poly(alkoxyanilines) compared with their respective poly(alkylanilines). The larger localization length in poly(o-alkoxyaniline) materials is thought to arise from decreased Coulomb interaction between the positive charge on the polymer chain and the anion; this interaction is reduced by the electron donating nature of the alkoxy groups. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：817 / 822

页数：6

共 14 条

[1]

Aprano GD, 1995, CHEM MATER, V7, P33

[2] COUNTERION INDUCED PROCESSIBILITY OF CONDUCTING POLYANILINE AND OF CONDUCTING POLYBLENDS OF POLYANILINE IN BULK POLYMERS [J].