Synthesis and properties of tetra-alkyl-dimethylguanidinium salts as a potential new generation of ionic liquids

被引：153

作者：

Mateus, NMM ^{[1
]}

Branco, LC ^{[1
]}

Lourenço, NMT ^{[1
]}

Afonso, CAM ^{[1
]}

机构：

[1] Univ Nova Lisboa, REQUIMTE CQFB, Dept Quim, Fac Ciencias & Tecnol, P-2929516 Caparica, Portugal

来源：

GREEN CHEMISTRY | 2003年 / 5卷 / 03期

关键词：

D O I：

10.1039/b303408a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New room temperature ionic liquids based on the tetra-alkyl-dimethylguanidinium cation present high stability under thermal, basic, acid, nucleophilic and oxidative conditions, low temperature glass transition phases and peculiar solubility properties in common solvents.

引用

页码：347 / 352

页数：6

共 41 条

[1] Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Munro, HL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2001, (19) :2010-2011

[2] The role of hydrogen bonding in controlling the selectivity of Diels-Alder reactions in room-temperature ionic liquids [J].

Aggarwal, A ;

Lancaster, NL ;

Sethi, AR ;

Welton, T .

GREEN CHEMISTRY, 2002, 4 (05) :517-520

[3] Unexpected side reactions of imidazolium-based ionic liquids in the base-catalysed Baylis-Hillman reaction [J].

Aggarwal, VK ;

Emme, I ;

Mereu, A .

CHEMICAL COMMUNICATIONS, 2002, (15) :1612-1613

[4] An investigation of the radiochemical stability of ionic liquids [J].

Allen, D ;

Baston, G ;

Bradley, AE ;

Gorman, T ;

Haile, A ;

Hamblett, I ;

Hatter, JE ;

Healey, MJF ;

Hodgson, B ;

Lewin, R ;

Lovell, KV ;

Newton, B ;

Pitner, WR ;

Rooney, DW ;

Sanders, D ;

Seddon, KR ;

Sims, HE ;

Thied, RC .

GREEN CHEMISTRY, 2002, 4 (02) :152-158

[5] Ionic liquids as matrixes for matrix-assisted laser desorption/ionization mass spectrometry [J].

Armstrong, DW ;

Zhang, LK ;

He, LF ;

Gross, ML .

ANALYTICAL CHEMISTRY, 2001, 73 (15) :3679-3686

[6] CO2 capture by a task-specific ionic liquid [J].

Bates, ED ;

Mayton, RD ;

Ntai, I ;

Davis, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (06) :926-927

[7]

Branco LC, 2002, CHEM-EUR J, V8, P3671, DOI 10.1002/1521-3765(20020816)8:16<3671::AID-CHEM3671>3.0.CO

[8]

2-9

[9]

Branco LC, 2002, CHEM-EUR J, V8, P3865, DOI 10.1002/1521-3765(20020902)8:17<3865::AID-CHEM3865>3.0.CO

[10]

2-L

← 1 2 3 4 5 →