In situ anomalous small angle X-ray scattering and absorption on an operating rechargeable lithium ion battery cell

被引：13

作者：

Braun, A

Seifert, S

Thiyagarajan, P

Cramer, SP

Cairns, EJ

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA

[2] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

[3] Argonne Natl Lab, Div Intense Pulsed Neutron Source, Argonne, IL 60439 USA

[4] Univ Calif Davis, Dept Appl Sci, Davis, CA 95616 USA

[5] Lawrence Berkeley Lab, Phys Biosci Div, Berkeley, CA 94720 USA

[6] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2001年 / 3卷 / 03期

关键词：

ASAXS; microstructure; lithium battery; in situ;

D O I：

10.1016/S1388-2481(01)00121-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We have employed anomalous small angle X-ray scattering (ASAXS) and X-ray absorption in situ on an operating lithium ion battery, cell with LiMn2O4 as the positive electrode material. Manganese K-edge absorption spectra and scattering patterns were recorded at various stages of charge between 3.8 and 4.5 V. The shift of the manganese absorption K-edge was observed as a function of the charge of the electrode, Clear changes in the microstructure of the spinel at the 4V plateau was observed even during the first charging cycle. (C) 2001 Published by Elsevier Science B.V.

引用

页码：136 / 141

页数：6

共 15 条

[1] X-ray scattering and adsorption studies of thermally oxidized glassy carbon [J].