Gold as an alloying element promoting formation of a nanoicosahedral phase in a Cu-based alloy

被引:26
作者
Louzguine, DV [1 ]
Inoue, A [1 ]
机构
[1] Tohoku Univ, Inst Mat Res, Aoba Ku, Sendai, Miyagi 9808577, Japan
关键词
amorphous materials; quasicrystals; crystal structure; thermal analysis; TEM;
D O I
10.1016/S0925-8388(03)00409-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present paper presents a new application field of Au as an alloying element in Cu-based glassy alloys with a tendency to form nanoscale icosahedral particles having quasicrystalline symmetry upon devitrification. Nanoicosahedral particles with a size below 10 nm are formed in the amorphous matrix of Cu55Zr30Ti10Au5 glassy alloy in the initial stage of the devitrification process. The paper also illustrates structure changes on heating studied by X-ray diffraction, transmission electron microscopy, differential scanning and isothermal calorimetry methods. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:153 / 156
页数:4
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