Heterometallic borole complexes of iron and gold

被引：11

作者：

Braunstein, P ^{[1
]}

Herberich, GE

Neuschutz, M

Schmidt, MU

Englert, U

Lecante, P

Mosset, A

机构：

[1] Univ Strasbourg 1, Chim Coordinat Lab, CNRS, UMR 7513, F-67070 Strasbourg, France

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany

[3] CNRS, Ctr Elaborat Mat & Etud Struct, F-31055 Toulouse, France

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 11期

关键词：

D O I：

10.1021/om9703189

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first heterometallic borole complexes of Fe and Au have been prepared by reaction of [HFe{eta(5)-(1-phenylborole)}(CO)(2)](-) (1) with [AuCl(PPh3)] in CH2Cl2, and the crystal structure of [(OC)(2){eta(5)-(1-phenylborole)}Fe{Au(PPh3)}(2)] (2) reveals an interesting orientation of the borole ligand. This complex reacts with [AuCl(PPh3)]/TIPF6 in CH2Cl2 to give the new cationic FeAu3 cluster [(OC)(2){eta(5)-(1-phenylborole)}Fe{Au(PPh3)}(3)]PF6 (4) which has a tetrahedral metal core, as established by a wide angle X-ray scattering study.

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页码：2177 / 2182

页数：6

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